Biggoron

Ocarina of Time
Biggoron is a gigantic Goron who lives on top of Death Mountain in Ocarina of Time, and is a skilled blade maker. In fact, he made the most powerful weapon in the entire game: the Biggoron Sword. However, Link must go through a lengthy trading sequence in order to obtain this deadly blade. Biggoron has a little brother, Medigoron, who is also into the sword making business, although the quality of his blades is inferior compared to his older brother.

Majora's Mask
Biggoron makes cameo appearances in Oracle of Seasons and Majora's Mask.

Oracle of Seasons
Biggoron makes cameo appearances in Oracle of Seasons and Majora's Mask.

The Minish Cap
In The Minish Cap, Biggoron can nibble on your shield and make it a Mirror Shield.

Quote from The Minish Cap Biggoron figurine:

"This is a legendary Goron with a body bigger than a mountain. It is so big, in fact, that no one has ever seen it all at once."

Phantom Hourglass
In Phantom Hourglass, Biggoron was the name of the chief of Goron Island. Unlike past appearances, Biggoron is the size of an average Goron instead of being a giant. He is the father of Gongoron and he is also the one that gives you permission to enter Goron Temple.

Trivia

 * Wearing the Goron Mask while speaking to King Zora reveals that Biggoron and King Zora are best friends, and have known each other since childhood.
 * The name "Biggoron" is a portmanteau of the words "big" and "Goron", referring to his large size.